基本信息出版社：Academic Press
页码：796 页
出版日期：2004年04月
ISBN：0124414567
条形码：9780124414563
装帧：平装
正文语种：英语
外文书名：双原子分子光谱和动力学: 修订增补版

内容简介 在线阅读本书

This book is written for graduate students just beginning research, for theorists curious about what experimentalists actually can and do measure, and for experimentalists bewildered by theory. It is a guide for potential users of spectroscopic data, and uses language and concepts that bridge the frequency-and time-domain spectroscopic communities.

Key topics, concepts, and techniques include: the assignment of simple spectra, basic experimental techniques, definition of Born-Oppenheimer and angular momentum basis sets and the associated spectroscopic energy level patterns (Hund's cases), construction of effective Hamiltonian matrices to represent both spectra and dynamics, terms neglected in the Born-Oppenheimer approximation (situations intermediate between Hund's cases, spectroscopic perturbations), nonlinear least squares fitting, calculation and interpretation of coupling terms, semi-classical (WKB) approximation, transition intensities and interference effects, direct photofragmentation (dissociation and ionization) and indirect photofragmentation (predissociation and autoionization) processes, visualization of intramolecular dynamics, quantum beats and wavepackets, treatment of decaying quasi-eigenstates using a complex Heff model, and concluding with some examples of polyatomic molecule dynamics.

Students will discover that there is a fascinating world of cause-and-effect localized dynamics concealed beyond the reduction of spectra to archival molecular constants and the exact ab initio computation of molecular properties. Professional spectroscopists, kinetics, ab initio theorists will appreciate the practical, simplified-model, and rigorous theoretical approaches discussed in this book.

Key Features:

• A fundamental reference for all spectra of small, gas-phase molecules.

• It is the most up-to-date and comprehensive book on the electronic spectroscopy and dynamics of diatomic molecules.

• The authors pioneered the development of many of the experimental methods, concepts, models, and computational schemes described in this book.

- A fundamental reference for all spectra of small, gas-phase molecules.
- Emphasizes the role of perturbations in understanding the dynamics of isolated molecules.
- Includes new applications of interest to researchers in all areas of chemistry and materials science.
作者简介 Helene Lefebvre-Brion and Robert W. Field

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...presents a unique systematic and logical approach to crime scene processing. - Law Enforcement Technology .one of the most well-compiled, easy to read and understand, thorough and beautifully written books that can go a long way in making one a better crime scene investigator. - Internet Journal of Forensic Medicine

Review
...presents a unique systematic and logical approach to crime scene processing. - Law Enforcement Technology

.one of the most well-compiled, easy to read and understand, thorough and beautifully written books that can go a long way in making one a better crime scene investigator. - Internet Journal of Forensic Medicine